Definitions |
Aluminum
A1+3 + HnPO43-n = A1PO4+nH+ |
- One mole of Alum precipitates 1 mole phosphate
- Dosages tend to fall in the range of a 1 to 3 ion to phosphorus molar ratio.
- Theoretical minimum solubility at pH 6.3
- Good phosphorus yield in the range of pH 5.5 - 7.0
- Solubility dramatically increases logarithmically after pH 6.3
- Alkalinity addition may be needed in low-alkaline water.
- Too much may cause interference with Spectrometer Readings (>200 mg - A1/L)
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Calcium(Lime) |
- 10Ca+2+6PO43+2OH- = Ca10(PO4)6(OH)2 (Hydroxylapatite)
- Best Residuals achieved at pH <10.5
- Lime dosages to achieve phosphate removal approximately equals 1.5 times the total alkalinity (mg/L CaCO3).
- Cannot be used in conjunction with biological growth due to high pH values.
- When used with post-precipitation, pH adjustment is necessary to achieve discharge limitations (pH 6 to 9) Caution: High pH causes ammonia release and an odor problem.
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Conversions Factors - Equivalents |
- 1 Day = 1440 Min.
- 1 Gallon = 3785 ml.
- Freshwater = 8.33 lb./gal
- Wastewater = 8.34 lb./gal
- 1 cu.ft. water = 7.48 gal/water
- 1 PPM = 1 mg/L
- 1 MGD = 700 GPM
- 1 GPM = 500 lb./hr water
- 1 Gal Poultry DAF Sludge = 8 lb./gal (approx.)
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Iron (Ferrous and Ferric) |
- Fe+3+HnPO43-n = FePO4+nH+
3Fe+2+2HnPO43-n = Fe3(PO4)2+2nH+
- 1 mole Ferric Iron precipitates 1 mole phosphates
- 3 moles Ferrous Iron precipitates 2 moles phosphates
- Theoretical minimum solubility at pH 5.3
- Good Phosphorous Removal in range pH 4.0 to pH 6.0
After pH 6.0 Solubility increases logarithmically
Addition of Alkalinity may be needed in low alkaline water.
- High Sludge Production
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Polymer Addition |
- 1 ml of 1% Polymer Solution added to 500ml Water Sample = 20 PPM
- 1 ml of .9% Polymer Solution added to 500ml Water Sample = 18 PPM
- 1 ml of .8% Polymer Solution added to 500ml Water Sample = 16 PPM
- 1 ml of .7% Polymer Solution added to 500ml Water Sample = 14 PPM
- 1 ml of .6% Polymer Solution added to 500ml Water Sample = 12 PPM
- 1 ml of .5% Polymer Solution added to 500ml Water Sample = 10 PPM
- 1 ml of .4% Polymer Solution added to 500ml Water Sample = 8 PPM
- 1 ml of .3% Polymer Solution added to 500ml Water Sample = 6 PPM
- 1 ml of .2% Polymer Solution added to 500ml Water Sample = 4 PPM
- 1 ml of .1% Polymer Solution added to 500ml Water Sample = 2 PPM
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Polymer Dosage (Formula) |
In lbs./ dry ton sludge = 2000 * (% polymer solution) * (volume polymer solution)
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(% sludge solids) * (volume sludge)
- To figure volume of any vertical round tank-
- v = pi * r 2 * h
- v = volume of tank
- pi = 3.14
- r = radius of tank
- h = height of tank
- 1 cu. ft. = 7.48 gal
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Polymer Solution Decimal - Equivalents |
- .1 % = .001
- .2 % = .002
- .25 % = .0025
- .3 % = .003
- .4 % = .004
- .5 % = .005
- .6 % = .006
- .7 % = .007
- .8 % = .008
- .9 % = .009
- 1.0 % = .01
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Pump Sizing for Dry Polymers |
- Flow from plant in GPM
- Multiply by 8.34 Lbs./Gal (for Wastewater)
- Divide by 1,000,000
- Multiply by the ppm dosage found from jar test
- Equals pounds of neat polymer per minute
- Divide by desired percentage make-up solution of polymer
- Equals lbs. of water needed per minute
- Divide by 8.33 Lbs. /Gal (for Fresh water)
- Equals Gal/Min of polymer solution needed
- To run Pump in 50 % range, multiply by 2. This will give you the maximum capacity needed for the pump.
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Pump Sizing for Liquid Polymers |
- Flow from plant in GPM
- Multiply by 8.34 Lbs./Gal (for Wastewater)
- Divide by 1,000,000
- Multiply by the ppm dosage found from jar test
- Equals pounds of neat polymer per minute
- Divide by weight of neat polymer per gallon
- Equals gals/min of neat polymer
- Divide by desired percentage make-up solution of polymer
- Equals Gal/Min of polymer solution needed
- To run Pump in 50 % range, multiply by 2. This will give you the maximum capacity needed for the pump.
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